General Chemistry - MCAT Chemical and Physical Foundations of Biological Systems

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Question

Consider the following reaction.

What is the oxidizing reagent in the reaction?

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Answer

The oxidizing reagent is the reactant, not the atom, that is responsible for receiving electrons from another atom in order to oxidize it. The oxygen gas goes from having an oxidation number of 0 to –2. This means that oxygen gas is reduced, but because it oxidized another atom by taking its electrons, we call it the oxidizing reagent.

Reactant oxygen is elemental, and has oxidation number 0.

Product oxygen is in H2O, with net charge of 0.

Total charge = 2(H) + (O) = 0

2(+1) + (O) = 2 + (O) = 0

O = –2

Decrease in oxidation number indicates reduction, and also identifies the oxidizing agent.

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